Document Type

Thesis

Date of Award

6-30-1967

Degree Name

Master of Science in Chemical Engineering - (M.S.)

Department

Chemical Engineering

First Advisor

Jerome J. Salamone

Second Advisor

Saul I. Kreps

Third Advisor

Dimitrios P. Tassios

Abstract

A concentric cylinder type cell was designed and constructed tp measure thermal conductivity of liquids. The materials of construction were stainless steel and teflon, so that a wide variety of liquids could be tested.

The systems studied were aqueous solutions of methyl alcohol, ethyl alcohol, n-propyl alcohol, isopropyl alcohol, and tertiary-butyl alcohol. Thermal conductivity was studied as a function of composition.

The data obtained were fitted to quadratic equations by least squares analysis. For each system, an equation of the following type was obtained:

kL = A + BxA + CxA2

where kL is thermal conductivity, xA is weight fraction of alcohol, and A, B, and C are constants. The table below give values of A, B, and C for each system. COMPONENT AABCMethyl Alcohol.369-.404.149Ethyl Alcohol.365-.460.169n-Propyl Alcohol.363-.497.222Isopropyl Alcohol.370-.508.211tertiary-Butyl Alcohol.375-.563.248

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