Document Type

Thesis

Date of Award

8-31-1991

Degree Name

Master of Science in Electrical Engineering - (M.S.)

Department

Electrical and Computer Engineering

First Advisor

Ken K. Chin

Second Advisor

Roy H. Cornely

Third Advisor

Marek Sosnowski

Abstract

Electrical and optical properties of spin-coated THERMID polyimide EL-5010 have been studied and evaluated in this thesis. The D.C. bulk resistivities of 0.96-2.56 μm thick samples were measured to be 1016 Ω-cm over the 27-160°C range using a test system consisting of Keithley 236 Source-Measure Unit. The bulk resistivity decreased to 2 x 1014Ω-cm at 200?C. The surface resistivity, 1015Ω/0 , and breakdown voltage, 350 V/pm, were also measured. The fixed charge concentration and mobile ion concentration in the THERMID polyimide EL-5010 insulator of a MIS capacitor structure were measured using a high frequency C-V measurement technique. The measured value of the positive mobile ion concentration was 1.12 x 1011cm-2 and of the fixed charge was found to be negative with a value of 1011 cm-2. The transmission spectrum over the wave number range of 1-10 cm-1 was obtained using a test system consisting of a mercury lamp, a lamellar grating, and a dip-stick helium-cooled bolometer. The transmission spectrum for the wave number range of 10-60 cm-1 was obtained using a test system consisting of a Synchrotron far infrared light source, a Nicolet Michelson scanning spectrometer, and a pumped helium-cooled detector. In the wave number range of 1-25 cm-1, the far infrared absorption of the THERMID polyimide EL-5010 increased with the increasing of wave number and reached the maximum at wave number 25cm-1. In the wave number range of 25-60 cm-1, almost no transmission occurred. Mechanisms responsible for these electrical and optical properties are discussed.

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