Document Type

Thesis

Date of Award

9-30-1984

Degree Name

Master of Science in Chemical Engineering - (M.S.)

Department

Chemical Engineering and Chemistry

First Advisor

Wing T. Wong

Second Advisor

Chen-Chong Lin

Third Advisor

Joseph W. Bozzelli

Abstract

Homogeneous reduction of sulfur dioxide by carbon monoxide was investigated in the temperature range between 700 and 1000°C, initial sulfur dioxide concentration of about 3000 ppm, typical of a flue gas from coal fired power plants, and excess carbon monoxide concentration, in a 12 mm O.D. quartz tubular reactor. Over ninty percent reduction of sulfur dioxide was obtained at temperatures above 900°C and space times of the order of about 3.5 seconds. Substantial carbonyl sulfide was also produced.

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