Document Type

Thesis

Date of Award

5-31-1974

Degree Name

Master of Science in Chemical Engineering - (M.S.)

Department

Chemical Engineering and Chemistry

First Advisor

Edward Charles Roche, Jr.

Second Advisor

John E. McCormick

Third Advisor

Dimitrios P. Tassios

Abstract

This work deals with the recovery of solvents from a complex process waste stream containing methylene chloride chloroform, n-propyl alcohol, isopropyl alcohol, heptane and butyl acetate. In addition to the above-mentioned solvents, the mixture is saturated with water (ca. 1%), hydrochloric acid, and contains organic and inorganic process impurities. The objective was to develop the simplest economical recovery process utilizing vapor-liquid equilibrium data, distillation and extraction procedures. Considerable effort was expended to develop precise and reliable assay methods. A process which met the necessary requirements of maximum solvent recovery with minimum waste disposal, was developed.

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