Thermal decomposition of dichloromethane/1,1,1-trichloroethane mixture in an atmosphere of hydrogen

Document Type

Conference Proceeding

Publication Date

12-1-1988

Abstract

In this study, a dichloromethane/1,1,1-trichloroethane mixture was used as a model chlorocarbon system to investigate the thermal reductive processes of chlorocarbons with hydrogen. The reactions were studied in a tubular reactor at a total pressure of 1 atm with residence times of 0.05 - 2.0 sec. in the temperature range 475 - 810°C. The objective of this study is to examine the high temperature hydrodechlorination and thermal reactions of a CH2Cl2/CH3CCl3 mixture in a tubular flow system characterize product distributions determine if complete and facile conversion to HCl is achievable, and enhance understanding of thermal reaction kinetics of chlorocarbons (C,H,Cl systems).

Identifier

0024166784 (Scopus)

Publication Title

American Society of Mechanical Engineers Heat Transfer Division Publication HTD

ISSN

02725673

First Page

131

Last Page

135

Issue

PT2

Volume

104

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