Measurement of the spin Hamiltonian parameters of Cu2+ ion in Zn2+-doped CaCd(CH3COO)4·6H2O
Document Type
Article
Publication Date
1-1-1999
Abstract
The spin Hamiltonian parameters (g∥, g⊥, A∥ and A⊥) of Cu2+ in Zn2+-doped CCDAH have been determined in the temperature range of 300 K to 15 K. The temperature variation of the normalized intensity of the Cu2+ hyperfine lines was also studied in the above temperature range. Our data show that g∥, A∥ and A⊥ values are unaffected by the presence of Zn2+ impurities in the crystal, while the g⊥ changes significantly from the corresponding values previously reported for pure CCDAH (i.e., without Zn2+ doping). While g∥ varied slightly with temperature (from 2.366 at 300 K to 2.351 at 15 K), g⊥ remained virtually unaffected by temperature. ©1999 Publication Board, Japanese Journal of Applied Physics.
Identifier
0032664529 (Scopus)
Publication Title
Japanese Journal of Applied Physics Part 1 Regular Papers and Short Notes and Review Papers
External Full Text Location
https://doi.org/10.1143/jjap.38.2753
ISSN
00214922
First Page
2753
Last Page
2754
Issue
5 A
Volume
38
Recommended Citation
Oguama, Ferdinand A. and Shields, Howard W., "Measurement of the spin Hamiltonian parameters of Cu2+ ion in Zn2+-doped CaCd(CH3COO)4·6H2O" (1999). Faculty Publications. 16074.
https://digitalcommons.njit.edu/fac_pubs/16074