Date of Award
Master of Science in Chemical Engineering - (M.S.)
Chemical Engineering and Chemistry
Dimitrios P. Tassios
Ernest N. Bart
Analytical evaluations of the second and third derivatives of the molar Gibbs energy of mixing for the NRTL/LEMF equations indicate distinct zones of miscible and inmiscible prediction.
These calculations for a number of different α's have produced approximate miscibility limits for both NRTL/LEMF energy parameters and infinite dilution activity coefficients of a given system.
Petrie, Robert, "A preliminary study of the thermodynamic limitations of the NRTL/LEMF equations" (1975). Theses. 2131.