Date of Award
Master of Science in Chemical Engineering - (M.S.)
Chemical Engineering and Chemistry
Robert G. Poetz
Howard S. Kimmel
The thermal dehydration of MgSO3.3H2O and MgSO3.6H2O have been studied by differential thermal analysis, differential scanning calorimetry and thermal gravimetric analysis.
Similar studies by other groups led to contradictory conclusions. In this investigation, these results were reconciled and it was concluded that MgSO3.6H2O, under equilibrium conditions, dehydrates in two steps through the intermediate formation of MgSO3.3H2O.
One consequence of this work is the development of a simple analytical procedure, using TGA, for the quantitative determination of both hydrates in mixtures and in the presence of thermally inactive material.
Abdel-Malek, Raafat F., "The thermal dehydration of magnesium sulfate hexahydrate (MgSO3.6H2O) and magnesium sulfite trihydrate (MgSO3.3H2O)" (1975). Theses. 2074.