Document Type


Date of Award


Degree Name

Master of Science in Environmental Science - (M.S.)


Chemical Engineering, Chemistry and Environmental Science

First Advisor

Barbara B. Kebbekus

Second Advisor

Joseph W. Bozzelli

Third Advisor

Arthur Greenberg


Volatile organics in ambient air were regularly collected on Tenax cartridges at high (10 ml/min) and low (5 ml/min) intake flows. These Tenax samples were analyzed by using a Tekmar Automatic Thermal Desorber and capillary GC system with parallel flame ionization (FID) and electron capture detectors (ECD). A series of quality assurance procedures has been established to improve and assure the accuracy and precision of sample collector and analysis. These procedures relate to performance of the Tekmar thermal desorber, recovery efficiency from the Tenax, and include studies on breakthrough and co-elution. The results demonstrate (1) that from ambient air data in East Central New Jersey, chlorocarbons, including chloroform, 1,1,1-trichloroethane, carbon tetrachloride, trichloroethylene and perchloroethylene, are present at lower levels than the hydrocarbons: hexane, benzene, toluene and p,m-xylene. Among the chlorocarbons, chloroform and trichloroethylene are present at very low trace levels (within 0.5 ppb) at sampling sites if compared to the other compounds; (2) the ECD is a preferred detector to accurately quantitate the chloro compounds, while hydrocarbons are bset quantitated by FID; (3) The accuracy and precision of Tenax sampling for most of the target compounds warrants its use as judged from studies of breakthrough as well as agreement between high and low flow samples; and (4) Tenax adsorbent is unable to efficiently trap light chlorocarbons such as methylchloride and dichloromethane. A statistical analysis of air data is presented based upon the above studies.



To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.