Molecular hydrogen assisted transport of H atoms

Document Type

Article

Publication Date

10-8-2010

Abstract

Transport of hydrogen atoms plays a key role in chemical and biological processes involving metabolism of molecular hydrogen. Several 'gas-phase' and more intricate organometallic models (mimics of the hydrogenase enzyme) are developed to show the intriguing role of the molecular hydrogen as a third party in the pass-on transfer of hydrogen atoms. This hydrogen assisted transport (HAT) mechanism is based on the current understanding of the hydrogen exchange reactions and it is believed to be applicable to certain H/D-isotope exchange processes and remote transport of H-atoms. © Published by Elsevier B.V.

Identifier

77957315515 (Scopus)

Publication Title

Chemical Physics Letters

External Full Text Location

https://doi.org/10.1016/j.cplett.2010.09.003

ISSN

00092614

First Page

263

Last Page

269

Issue

4-6

Volume

498

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