Optical properties of Ge nanowires grown on silicon (100) and (111) substrates

Document Type

Conference Proceeding

Publication Date

12-13-2005

Abstract

We report Raman scattering and photoluminescence (PL) measurements of Ge nanowires (NWs) grown by chemical vapor deposition on silicon substrates with (100) and (111) crystallographic orientations. A sharp and narrow Raman peak at ∼ 300 cm -1 indicates single-crystal quality of Ge NWs ∼40 nm in diameter and approximately a micrometer in length. The absence of Si-Ge vibrations in Raman spectra shows that SiGe interdiffusion is insignificant for most of the NW volume. Low temperature PL spectra and the PL intensity-temperature dependence strongly indicate that the observed emission originates mostly at Ge NW Si substrate interfaces, where Si-Ge intermixing has been detected. We found that such interfaces are formed differently for (111) and (100) oriented Si substrates due to the strongly oriented <111> preferential growth direction of Ge NWs.

Identifier

28544445206 (Scopus)

Publication Title

Proceedings Electrochemical Society

First Page

49

Last Page

56

Volume

PV 2004-13

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