Author ORCID Identifier

0000-0003-1255-1240

Document Type

Dissertation

Date of Award

8-31-2024

Degree Name

Doctor of Philosophy in Environmental Engineering - (Ph.D.)

Department

Civil and Environmental Engineering

First Advisor

Wen Zhang

Second Advisor

Taha F. Marhaba

Third Advisor

Dibakar Datta

Fourth Advisor

Zhiyong Jason Ren

Fifth Advisor

Lucia Rodriguez-Freire

Abstract

Multifunctional, modular, and scalable water treatment technologies that operate without chemical additives are crucial for addressing global water pollution challenges. While traditional membrane-based separation processes are crucial for ensuring clean water supplies, they primarily focus on pollutant removal rather than on the upcycling of pollutants into valuable resources. Electrified membrane filtration presents a robust alternative, utilizing minimal or no chemical additives and harnessing electrical power to directly reduce contaminants or produce reactive oxidants or reductants on-site.

This dissertation is dedicated to the development of innovative electrochemically reactive membranes designed to address three major challenges: (1) the engineering of electrocatalysts with optimized electronic structures, tailored reaction microenvironments, and refined electrode interfaces; (2) the electrocatalytic upcycling of target waste streams into value-added products and product separation by electrified membrane, thereby aiding in environmental pollution control and nutrient recovery; and (3) the design of flow-type electrified membrane electrolyzer that ensure high efficiency, atomic economy, and economic feasibility. These advancements aim to enhance the efficacy and sustainability of water treatment systems.

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