Document Type

Dissertation

Date of Award

Spring 5-31-1988

Degree Name

Doctor of Engineering Science in Chemical Engineering

Department

Chemical Engineering, Chemistry and Environmental Science

First Advisor

Gordon Lewandowski

Second Advisor

Piero M. Armenante

Third Advisor

Samir S. Sofer

Fourth Advisor

Basil Baltzis

Fifth Advisor

John W. Liskowitz

Abstract

Various nutrient media and reactor configurations have been explored in order to grow the white rot fungus Phanerochaete chrysosporium, induce its active enzyme, develop kinetic data for the degradation of 2-chlorophenol, and use chemical engineering analysis to design an efficient reactor.

Preliminary experiments indicated that the biodegradation rate was improved by two to three orders of magnitude when the fungus was immobilized. As a result, emphasis shifted to two types of reactor design: a packed-bed reactor employing a silica-based porous support, and a fluidized-bed reactor employing alginate beads. Both were very effective in degrading 2 chlorophenol at inlet concentrations up to 520 ppm. Apparent Michaelis-Menten kinetic rate constants were developed for both reactors. To our knowledge, these are the first such constants to be published for this fungus.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.