Document Type

Thesis

Date of Award

1-31-1990

Degree Name

Master of Science in Chemistry - (M.S.)

Department

Chemical Engineering, Chemistry and Environmental Science

First Advisor

Arthur Greenberg

Second Advisor

Barbara B. Kebbekus

Third Advisor

R. P. T. Tomkins

Abstract

A rapid, simple method for routine trace analysis of four isomeric nitropolycyclic aromatic hydrocarbons (nitro-PAH) (1-nitropyrene, 2-nitropyrene, 2-nitrofluoranthene and 3-nitrofluoranthene) in ambient air particulate matter is described. Two types of air particle sample (TSP and IP10) were collected and particle extracts were prefractionated by thin layer chromatography and the appropriate zones of interest analyzed by reversed-phase HPLC with UV and fluorescence detection. The study of Zn/Si post-column reaction chamber and oxygen scrubber for catalytic reduction of target compounds is also described. Six nitro-PAH compounds were identified in TSP and five in IP10 air particle samples. The results of identification and quantification are discussed.

Included in

Chemistry Commons

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