Dynamic covalent and noncovalent assembly of o-nitrosocumene in organic solvents and water

Authors

Cory H. Rogers, The University of Alabama
Anu Pradeep, College of Arts and Sciences
Layla A. Galiano, The University of Alabama
S. Ariel Kelley, The University of Alabama
Ramkumar Varadharajan, College of Arts and Sciences
Ken Belmore, The University of Alabama
Logan M. Whitt, The University of Alabama
Yanmei Li, New Jersey Institute of Technology
Pier Alexandre Champagne, New Jersey Institute of Technology
Vaidhyanathan Ramamurthy, College of Arts and Sciences
Silas C. Blackstock, The University of Alabama

Document Type

Article

Publication Date

11-5-2024

Abstract

ortho-Nitrosocumene (o-NC) exhibits dynamic N,N bonding, interchanging monomer and E/Z-azodioxide dimer structures, the extent of which depends on the environment. As a solid, o-NC is a Z-dimer; in organic solvent, the monomer is favored; and in water, dimers are favored. A supramolecular assembly of o-NC is observed as a separate species by NMR in water, shown to be a novel nanometer-sized aggregate containing ~2000 molecules.

Identifier

85209125210 (Scopus)

Publication Title

Chemical Communications

External Full Text Location

https://doi.org/10.1039/d4cc03955f

e-ISSN

1364548X

ISSN

13597345

PubMed ID

39499547

First Page

13899

Last Page

13902

Issue

94

Volume

60

Recommended Citation

Rogers, Cory H.; Pradeep, Anu; Galiano, Layla A.; Kelley, S. Ariel; Varadharajan, Ramkumar; Belmore, Ken; Whitt, Logan M.; Li, Yanmei; Champagne, Pier Alexandre; Ramamurthy, Vaidhyanathan; and Blackstock, Silas C., "Dynamic covalent and noncovalent assembly of o-nitrosocumene in organic solvents and water" (2024). Faculty Publications. 97.
https://digitalcommons.njit.edu/fac_pubs/97