Magnesium Regulates the Circadian Oscillator in Cyanobacteria

Document Type

Article

Publication Date

8-1-2019

Abstract

The circadian clock controls 24-h biological rhythms in our body, influencing many time-related activities such as sleep and wake. The simplest circadian clock is found in cyanobacteria, with the proteins KaiA, KaiB, and KaiC generating a self-sustained circadian oscillation of KaiC phosphorylation and dephosphorylation. KaiA activates KaiC phosphorylation by binding the A-loop of KaiC, while KaiB attenuates the phosphorylation by sequestering KaiA from the A-loop. Structural analysis revealed that magnesium regulates the phosphorylation and dephosphorylation of KaiC by dissociating from and associating with catalytic Glu residues that activate phosphorylation and dephosphorylation, respectively. High magnesium causes KaiC to dephosphorylate, whereas low magnesium causes KaiC to phosphorylate. KaiC alone behaves as an hourglass timekeeper when the magnesium concentration is alternated between low and high levels in vitro. We suggest that a magnesium-based hourglass timekeeping system may have been used by ancient cyanobacteria before magnesium homeostasis was established.

Identifier

85068059595 (Scopus)

Publication Title

Journal of Biological Rhythms

External Full Text Location

https://doi.org/10.1177/0748730419851655

e-ISSN

15524531

ISSN

07487304

PubMed ID

31216910

First Page

380

Last Page

390

Issue

4

Volume

34

Grant

DMS-1412877

Fund Ref

National Science Foundation

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