Thermochromism in polydiacetylene-metal oxide nanocomposites

Document Type

Article

Publication Date

4-14-2012

Abstract

Irreversible and reversible chromatic transitions during heating and cooling cycles were investigated in polydiacetylene poly-PCDA (poly-10,12-pentacosadiynoic acid) composites with nanocrystalline zinc oxide (ZnO), titanium oxide (TiO 2), zirconium oxide (ZrO 2) and ZnO and ZrO 2 alloys. In contrast to pure poly-PCDA, poly-PCDA composites with nanocrystalline ZnO displayed rapid reversibility on thermal cycling, whereas the corresponding composites with nanocrystalline TiO 2 and ZrO 2 were irreversible, and poly-PCDA composites with thermally prepared ZnO and ZrO 2 alloys displayed slower reversibility. The mechanism of reversible and irreversible thermochromism in these materials was explored using Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC) and X-ray absorption fine structure (XAFS) spectroscopy. In pure poly-PCDA, heating leads to an irreversible strain on the polymer backbone to form a red phase, which is not released on cooling. In the presence of ZnO evidence is provided for chelation involving the side chain head groups which can release strain on cooling to rapidly form the blue phase. Chemical interaction coupled with reversible behavior was however observed only when the composites were prepared with ZnO having an average crystallite size of 300 nm and below with a fraction of an amorphous grain boundary phase. Poly-PCDA composites with ZnO/ZrO 2 alloys showing slower thermochromic reversibility can be used both as temperature and elapsed time-temperature sensors. © The Royal Society of Chemistry 2012.

Identifier

84858734601 (Scopus)

Publication Title

Journal of Materials Chemistry

External Full Text Location

https://doi.org/10.1039/c2jm16175c

e-ISSN

13645501

ISSN

09599428

First Page

7028

Last Page

7035

Issue

14

Volume

22

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