Enantioselective addition of diethylzinc to aldehydes catalyzed by a β-amino alcohol derived from (+)-3-carene

Document Type

Article

Publication Date

7-4-2003

Abstract

A (+)-3-carene derived aminoalcohol was successfully used as a chiral ligand in the catalytic enantioselective diethylzinc addition to various aldehydes. Very high enantiomeric excess (up 98% in 1-(2-methoxyphenyl)-1-propanol) was obtained. A plausible mechanism has been suggested for the observed enantioselectivity. © 2003 Elsevier Science Ltd. All rights reserved.

Identifier

0037756810 (Scopus)

Publication Title

Tetrahedron Asymmetry

External Full Text Location

https://doi.org/10.1016/S0957-4166(03)00347-1

ISSN

09574166

First Page

1763

Last Page

1766

Issue

13

Volume

14

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