Broadening the reactivity spectrum of a phthalocyanine catalyst while suppressing its nucleophilic, electrophilic and radical degradation pathways

Document Type

Article

Publication Date

5-21-2011

Abstract

A robust molecule that resists degradation via nucleophilic, electrophilic and radical attacks is described. Coordinated O2 is reduced catalytically, producing efficiently thyil radicals in spite of the extreme electronic deficiency of the catalyst. © 2011 The Royal Society of Chemistry.

Identifier

79955398050 (Scopus)

Publication Title

Dalton Transactions

External Full Text Location

https://doi.org/10.1039/c1dt10458f

e-ISSN

14779234

ISSN

14779226

First Page

5162

Last Page

5165

Issue

19

Volume

40

Grant

0967934

Fund Ref

National Science Foundation

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